Cans of compressed air get cold while they re discharging because of a thermodynamic principle known as the adiabatic effect.
Why does compressed air get cold when released.
Then the gas is released through a nozzle the gas expands again and cools.
A gas initially at high pressure cools significantly when that pressure is released.
Minutephysics knows the actual reason why compressed air cans become so cold and will explain it.
If the container is stored the temperature equalizes to the ambient temperature.
The cold temperature profile sneaks back towards the can because the air is such a lousy conductor of heat so the heat is all coming from the can.
Eventually your hand gets cold.
The secret behind this freezing property of the cans is the do not shake warning that is mentioned on the can.
The video will explain what really happens inside the compressed air cans.
Travelling along this pressure gradient the gas expands and does work and this removes energy from the gas.
When air or other gas is compressed work is done and the gas heats up.
The reason the can gets cold after being used is due to a process known as adiabatic cooling a property of thermodynamics.
This is the principle operation of air conditioners refrigerators and other heat pumps.
There is no reason that the compressed air tank should have a lower temperature in the compressed state when the pressure was not changed for a couple hours.